reviewChemical ScienceJan 1, 2020DIAMOND OA

Vitrimers: directing chemical reactivity to control material properties

Université Toulouse III - Paul Sabatier · Université Fédérale de Toulouse Midi-Pyrénées · +5 more institutions

PubMed
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Abstract

The development of more sustainable materials with a prolonged useful lifetime is a key requirement for a transition towards a more circular economy. However, polymer materials that are long-lasting and highly durable also tend to have a limited application potential for re-use. This is because such materials derive their durable properties from a high degree of chemical connectivity, resulting in rigid meshes or networks of polymer chains with a high intrinsic resistance to deformation. Once such polymers are fully synthesised, thermal (re)processing becomes hard (or impossible) to achieve without damaging the degree of chemical connectivity, and most recycling options quickly lead to a drop or even loss of…

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