reviewChemical ReviewsMay 15, 2020HYBRID OA

Water and Metal–Organic Frameworks: From Interaction toward Utilization

Tianjin University · State Key Laboratory of Chemical Engineering · +3 more institutions

PubMed
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Abstract

The steep stepwise uptake of water vapor and easy release at low relative pressures and moderate temperatures together with high working capacities make metal-organic frameworks (MOFs) attractive, promising materials for energy efficient applications in adsorption devices for humidity control (evaporation and condensation processes) and heat reallocation (heating and cooling) by utilizing water as benign sorptive and low-grade renewable or waste heat. Emerging MOF-based process applications covered are desiccation, heat pumps/chillers, water harvesting, air conditioning, and desalination. Governing parameters of the intrinsic sorption properties and stability under humid conditions and cyclic operation are…

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