articleACS NanoJul 29, 2020Closed access

Crystalline Carbon Nitride Supported Copper Single Atoms for Photocatalytic CO 2 Reduction with Nearly 100% CO Selectivity

University of Electronic Science and Technology of China · Huazhong Agricultural University

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Abstract

Single metal atom photocatalysts have received widespread attention due to the rational use of metal resources and maximum atom utilization efficiency. In particular, N-rich amorphous g-C3N4 is always used as a support to anchor single metal atoms. However, the enhancement of photocatalytic activity of g-C3N4 by introducing a single atom is limited due to the bulk morphology and the excess defects of amorphous g-C3N4. Here, we report crystalline g-C3N4 nanorod supported copper single atoms by molten salts and the reflux method. The prepared single Cu atoms/crystalline g-C3N4 photocatalyst (Cu-CCN) shows highly selective and efficient photocatalytic reduction of CO2 under the absence of any cocatalyst or…

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