Atomically precise alloy nanoclusters: syntheses, structures, and properties

Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles, providing unique opportunities for investigating the quantum effects and precise structure-property correlations at the atomic level. As a versatile strategy, alloying can largely improve the physicochemical performances compared to the corresponding homo-metal nanoclusters, and thus benefit the applications of such nanomaterials. In this review, we highlight the achievements of atomically precise alloy nanoclusters, and summarize the alloying principles and fundamentals, including the synthetic methods, site-preferences for different heteroatoms in the templates, and alloying-induced structure and property changes. First,…

• NN
  National Natural Science Foundation of China

  Awards: U1532141, 21631001, 21871001
• AU
  Anhui University
• AP
  Anhui Provincial Department of Education
• AF
  Air Force Office of Scientific Research