articleNature CommunicationsJan 10, 2022GOLD OA

Contact-electro-catalysis for the degradation of organic pollutants using pristine dielectric powders

Georgia Institute of Technology · Chinese Academy of Sciences · +4 more institutions

PubMed
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Abstract

Mechanochemistry has been studied for some time, but research on the reactivity of charges exchanged by contact-electrification (CE) during mechanical stimulation remains scarce. Here, we demonstrate that electrons transferred during the CE between pristine dielectric powders and water can be utilized to directly catalyze reactions without the use of conventional catalysts. Specifically, frequent CE at Fluorinated Ethylene Propylene (FEP) - water interface induces electron-exchanges, thus forming reactive oxygen species for the degradation of an aqueous methyl orange solution. Contact-electro-catalysis, by conjunction of CE, mechanochemistry and catalysis, has been proposed as a general mechanism, which has…

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