articleNature CommunicationsJan 17, 2022GOLD OA

Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color

DLDan LiYYYujie YangJYJie YangMFManman FangBZBen Zhong Tang

Tianjin University · Chinese University of Hong Kong, Shenzhen · +1 more institution

PubMed
Indexed incrossrefdoajpubmed

Abstract

Many luminescent stimuli responsive materials are based on fluorescence emission, while stimuli-responsive room temperature phosphorescent materials are less explored. Here, we show a kind of stimulus-responsive room temperature phosphorescence materials by the covalent linkage of phosphorescent chromophore of arylboronic acid and polymer matrix of poly(vinylalcohol). Attributed to the rigid environment offered from hydrogen bond and B-O covalent bond between arylboronic acid and poly(vinylalcohol), the yielded polymer film exhibits ultralong room temperature phosphorescence with lifetime of 2.43 s and phosphorescence quantum yield of 7.51%. Interestingly, the RTP property of this film is sensitive to the…

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Authors

6
  • DL
    Dan LiCorresponding

    Tianjin University

  • YY
    Yujie Yang

    Tianjin University

  • JY
    Jie Yang

    Tianjin University

  • MF
    Manman Fang

    Tianjin University

  • BZ
    Ben Zhong Tang

    Tianjin University, Chinese University of Hong Kong, Shenzhen

Topics & keywords

Keywords
  • Phosphorescence
  • Afterglow
  • Chromophore
  • Luminescence
  • Fluorescence
  • Aqueous solution
  • Hydrogen bond
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