reviewChemical ReviewsFeb 8, 2022GREEN OA

Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies

Cornell University · University of Wisconsin–Madison · +8 more institutions

PubMed
Indexed incrossrefpubmed

Abstract

Hydrogen energy-based electrochemical energy conversion technologies offer the promise of enabling a transition of the global energy landscape from fossil fuels to renewable energy. Here, we present a comprehensive review of the fundamentals of electrocatalysis in alkaline media and applications in alkaline-based energy technologies, particularly alkaline fuel cells and water electrolyzers. Anion exchange (alkaline) membrane fuel cells (AEMFCs) enable the use of nonprecious electrocatalysts for the sluggish oxygen reduction reaction (ORR), relative to proton exchange membrane fuel cells (PEMFCs), which require Pt-based electrocatalysts. However, the hydrogen oxidation reaction (HOR) kinetics is significantly…

Citation impact

500
total citations
FWCI
22.19
Percentile
100%
References
1,366
Citations per year

Authors

49

Topics & keywords

Keywords
  • Chemistry
  • Electrocatalyst
  • Alkaline fuel cell
  • Proton exchange membrane fuel cell
  • Catalysis
  • Electrochemistry
  • Electrochemical energy conversion
  • Membrane
UN Sustainable Development Goals
  • Affordable and clean energy
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