reviewChemical ReviewsFeb 8, 2022Closed access

Coordination-Directed Self-Assembly of Functional Polynuclear Lanthanide Supramolecular Architectures

Chinese Academy of Sciences · Fujian Institute of Research on the Structure of Matter

PubMed
Indexed incrossrefpubmed

Abstract

). Compared with the intensively investigated mononuclear Ln-complexes, polymetallic lanthanide supramolecular assemblies offer more structural superiority and functional advantages. In recent decades, significant progress has been made in polynuclear lanthanide supramolecules, varying from structural evolution to luminescent and magnetic functional materials. This review summarizes the design principles in ligand-induced coordination-driven self-assembly of polynuclear Ln-structures and intends to offer guidance for the construction of more elegant Ln-based architectures and optimization of their functional performances. Design principles concerning the water solubility and chirality of the lanthanide-organic…

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