articleAccounts of Chemical ResearchApr 8, 2022Closed access

Long-Lived Organic Room-Temperature Phosphorescence from Amorphous Polymer Systems

Nanyang Technological University · Chongqing University of Technology

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Abstract

ConspectusLong-lived organic room-temperature phosphorescence (RTP) materials have recently drawn extensive attention because of their promising applications in information security, biological imaging, optoelectronic devices, and intelligent sensors. In contrast to conventional fluorescence, the RTP phenomenon originates from the slow radiative transition of triplet excitons. Thus, enhancing the intersystem crossing (ISC) rate from the lowest excited singlet state (S1) to the excited triplet state and suppressing the nonradiative relaxation channels of the lowest excited triplet state (T1) are reasonable methods for realizing highly efficient RTP in purely organic materials. Over the past few decades, many…

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Topics & keywords

Keywords
  • Phosphorescence
  • Amorphous solid
  • Polymer
  • Materials science
  • Photochemistry
  • Chemistry
  • Chemical engineering
  • Organic chemistry
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