Oxygen Evolution Reaction in Energy Conversion and Storage: Design Strategies Under and Beyond the Energy Scaling Relationship

The oxygen evolution reaction (OER) is the essential module in energy conversion and storage devices such as electrolyzer, rechargeable metal-air batteries and regenerative fuel cells. The adsorption energy scaling relations between the reaction intermediates, however, impose a large intrinsic overpotential and sluggish reaction kinetics on OER catalysts. Developing advanced electrocatalysts with high activity and stability based on non-noble metal materials is still a grand challenge. Central to the rational design of novel and high-efficiency catalysts is the development and understanding of quantitative structure-activity relationships, which correlate the catalytic activities with structural and electronic…

• SJ
  Shanghai Jiao Tong University
• AR
  Army Research Laboratory