Superhydrophobic Fabrics Produced by Electrospinning and Chemical Vapor Deposition

A versatile method to produce superhydrophobic fabrics by combining electrospinning and initiated chemical vapor deposition (iCVD) is reported. In this study, poly(caprolactone) (PCL) was first electrospun and then coated with a thin layer of hydrophobic polymerized perfluoroalkyl ethyl methacrylate (PPFEMA) by iCVD. The hierarchical surface roughness inherent in the PCL electrospun mats and the extremely low surface free energy of the coating layer obtained by iCVD yields stable superhydrophobicity with a contact angle of 175° and a threshold sliding angle less than 2.5° for a 20 mg droplet. This PPFEMA-coated PCL mat was also shown to exhibit at least “grade 8” oleophobicity. Hydrophobicity was demonstrated…