articleAngewandte ChemieJul 23, 2015Closed access

Coupling Mo 2 C with Nitrogen‐Rich Nanocarbon Leads to Efficient Hydrogen‐Evolution Electrocatalytic Sites

Jilin University · State Key Laboratory of Inorganic Synthesis and Preparative Chemistry · +1 more institution

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Abstract

Abstract In our efforts to obtain electrocatalysts with improved activity for water splitting, meticulous design and synthesis of the active sites of the electrocatalysts and deciphering how exactly they catalyze the reaction are vitally necessary. Herein, we report a one‐step facile synthesis of a novel precious‐metal‐free hydrogen‐evolution nanoelectrocatalyst, dubbed Mo 2 C@NC that is composed of ultrasmall molybdenum carbide (Mo 2 C) nanoparticles embedded within nitrogen‐rich carbon (NC) nanolayers. The Mo 2 C@NC hybrid nanoelectrocatalyst shows remarkable catalytic activity, has great durability, and gives about 100 % Faradaic yield toward the hydrogen‐evolution reaction (HER) over a wide pH range (pH…

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