articleJournal of the American Chemical SocietyJun 2, 2022GREEN OA

A General Synthetic Method for High-Entropy Alloy Subnanometer Ribbons

Peking University · Hong Kong Polytechnic University · +2 more institutions

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Abstract

High-entropy alloys (HEAs) are attracting intensive attention due to their broad compositional tunability and interesting catalytic properties. However, precisely shaping the HEAs into suprathin low-dimensional nanostructures for achieving diverse applications remains an enormous challenge owing to their intrinsic thermodynamic instability. Herein we propose a new and general low-temperature method for incorporating up to eight metallic elements into one single-phase subnanometer ribbon to achieve the thinnest HEA metal materials in the world. We experimentally demonstrate that synthetic processes for suprathin HEA subnanometer ribbons (SNRs) include (1) different metal atom nucleation via galvanic exchange…

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292
total citations
FWCI
12.76
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100%
References
25
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Authors

10

Topics & keywords

Keywords
  • Overpotential
  • Density functional theory
  • Nucleation
  • Alloy
  • Chemistry
  • Crystallization
  • Nanowire
  • Electrochemistry
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