Spontaneous Construction of Nucleophilic Carbonyl‐Containing Interphase toward Ultrastable Zinc‐Metal Anodes
Central South University · Northwestern Polytechnical University · +1 more institution
Abstract
Abstract Multifunctional interfacial engineering on the Zn anode to conquer dendrite growth, hydrogen evolution, and the sluggish kinetics associated with Zn deposition is highly desirable for boosting the commercialization of aqueous zinc‐ion batteries. Herein, a spontaneous construction of carbonyl‐containing layer on a Zn anode (Zn@ZCO) is rationally designed as an ion redistributor and functional protective interphase. It has strong zincphilicity and dendrite suppression ability due to the significant interaction of the highly electronegative and highly nucleophilic carbonyl oxygen, favoring ion transport and homogenizing Zn deposition effectively. On the other side, the hydrogen bond formed by the proton…
Citation impact
- FWCI
- 30.56
- Percentile
- 100%
- References
- 53
Authors
9Topics & keywords
- Interphase
- Materials science
- Zinc
- Nucleophile
- Metal
- Anode
- Inorganic chemistry
- Photochemistry