Metalated covalent organic frameworks: from synthetic strategies to diverse applications
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Abstract
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials discovered in the early 21st century that have become an attractive class of emerging materials due to their high crystallinity, intrinsic porosity, structural regularity, diverse functionality, design flexibility, and outstanding stability. However, many chemical and physical properties strongly depend on the presence of metal ions in materials for advanced applications, but metal-free COFs do not have these properties and are therefore excluded from such applications. Metalated COFs formed by combining COFs with metal ions, while retaining the advantages of COFs, have additional intriguing properties and applications, and…
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Topics
Keywords
- Nanotechnology
- Covalent bond
- Crystallinity
- Materials science
- Flexibility (engineering)
- Porosity
- Chemistry
- Organic chemistry
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