Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and functionalization reactions

Although C-H functionalization is one of the simplest reactions, it requires the use of highly active and selective catalysts. Recently, C-H-active transformations using porous materials such as crystalline metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) as well as amorphous porous-organic polymers (POPs) as new emerging heterogeneous catalysts have attracted significant attention due to their promising activity and potential material tunability. These porous solids offer exceptional structural uniformity, facile tunability and permanent porosity. In addition, tuning the catalytic selectivity of these porous materials can be achieved through engineering their site microenvironments, such…

• UO
  University of Zabol

  Awards: IR-UOZ-GR-9381, IR-UOZ-GR-81751
• RU
  RUDN University
• IS
  Iran Science Elites Federation