articleAdvanced MaterialsAug 19, 2022Closed access

Fully Textured, Production‐Line Compatible Monolithic Perovskite/Silicon Tandem Solar Cells Approaching 29% Efficiency

University of Electronic Science and Technology of China · China Academy of Engineering Physics · +2 more institutions

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Abstract

Abstract Perovskite/silicon tandem solar cells are promising avenues for achieving high‐performance photovoltaics with low costs. However, the highest certified efficiency of perovskite/silicon tandem devices based on economically matured silicon heterojunction technology (SHJ) with fully textured wafer is only 25.2% due to incompatibility between the limitation of fabrication technology which is not compatible with the production‐line silicon wafer. Here, a molecular‐level nanotechnology is developed by designing NiO x /2PACz ([2‐(9H‐carbazol‐9‐yl) ethyl]phosphonic acid) as an ultrathin hybrid hole transport layer (HTL) above indium tin oxide (ITO) recombination junction, to serve as a vital pivot for…

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