articleAngewandte Chemie International EditionSep 10, 2022Closed access

A Bifunctional CdS/MoO 2 /MoS 2 Catalyst Enhances Photocatalytic H 2 Evolution and Pyruvic Acid Synthesis

Wuhan University of Technology · China University of Geosciences · +2 more institutions

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Abstract

Abstract The best use of photogenerated electrons and holes is crucial to boosting photocatalytic activity. Herein, a bifunctional dual‐cocatalyst‐modified photocatalyst is constructed based on CdS/MoO 2 /MoS 2 hollow spheres for hydrogen evolution coupled with selective pyruvic acid (PA) production from lactic acid (LA) oxidation. MoS 2 and MoO 2 are simultaneously obtained from the conversion of CdMoO 4 in one step. In a photocatalytic process, the MoS 2 and MoO 2 function as the reduction and oxidation centers on which photogenerated electrons and holes accumulate and are used for hydrogen evolution reaction (HER) and PA synthesis, respectively. By monitoring the intermediates, a two‐step single‐electron…

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