A review on lignin pyrolysis: pyrolytic behavior, mechanism, and relevant upgrading for improving process efficiency

Lignin is a promising alternative to traditional fossil resources for producing biofuels due to its aromaticity and renewability. Pyrolysis is an efficient technology to convert lignin to valuable chemicals, which is beneficial for improving lignin valorization. In this review, pyrolytic behaviors of various lignin were included, as well as the pyrolytic mechanism consisting of initial, primary, and charring stages were also introduced. Several parallel reactions, such as demethoxylation, demethylation, decarboxylation, and decarbonylation of lignin side chains to form light gases, major lignin structure decomposition to generate phenolic compounds, and polymerization of active lignin intermediates to yield…

• NN
  National Natural Science Foundation of China

  Award: 21774059
• CS
  China Scholarship Council

  Award: 202108320294
• PA
  Priority Academic Program Development of Jiangsu Higher Education Institutions