Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

Jayaramulu, Kolleboyina; Mukherjee, Soumya; Morales, Dulce M.; Dubal, Deepak P.; Nanjundan, Ashok Kumar; Schneemann, Andreas; Masa, Justus; Kment, Štěpán; Schuhmann, Wolfgang; Otyepka, Michal; Zbořil, Radek; Fischer, Roland A.

doi:10.1021/acs.chemrev.2c00270

reviewChemical ReviewsNov 1, 2022GREEN OA

Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

KJKolleboyina Jayaramulu SMSoumya Mukherjee DMDulce M. Morales DPDeepak P. Dubal AKAshok Kumar Nanjundan

Regional Centre of Advanced Technologies and Materials · Indian Institute of Technology Jammu · +8 more institutions

PubMed

Indexed incrossrefpubmed

Abstract

Current energy and environmental challenges demand the development and design of multifunctional porous materials with tunable properties for catalysis, water purification, and energy conversion and storage. Because of their amenability to de novo reticular chemistry, metal-organic frameworks (MOFs) have become key materials in this area. However, their usefulness is often limited by low chemical stability, conductivity and inappropriate pore sizes. Conductive two-dimensional (2D) materials with robust structural skeletons and/or functionalized surfaces can form stabilizing interactions with MOF components, enabling the fabrication of MOF nanocomposites with tunable pore characteristics. Graphene and its…

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Topics

Keywords

Graphene
Nanotechnology
Metal-organic framework
Chemistry
Energy transformation
Catalysis
Photocatalysis
Nanocomposite

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