articleAdvanced MaterialsDec 16, 2022Closed access

Over 19% Efficiency Organic Solar Cells by Regulating Multidimensional Intermolecular Interactions

Chinese Academy of Sciences · Qingdao Institute of Bioenergy and Bioprocess Technology · +5 more institutions

PubMed
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Abstract

Research on organic solar cells (OSCs) has progressed through material innovation and device engineering. However, well-known and ubiquitous intermolecular interactions, and particularly their synergistic effects, have received little attention. Herein, the complicated relationship between photovoltaic conversion and multidimensional intermolecular interactions in the active layers is investigated. These interactions are dually regulated by side-chain isomerization and end-cap engineering of the acceptors. The phenylalkyl featured acceptors (LA-series) exhibit stronger crystallinity with preferential face-on interactions relative to the alkylphenyl attached isomers (ITIC-series). In addition, the PM6 and…

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