Recent Advances in the Use of Covalent Organic Frameworks as Heterogenous Photocatalysts in Organic Synthesis

López‐Magano, Alberto; Daliran, Saba; Oveisi, Ali Reza; Mas‐Ballesté, Rubén; Dhakshinamoorthy, Amarajothi; Alemán, José; Garcı́a, Hermenegildo; Luque, Rafael

doi:10.1002/adma.202209475

reviewAdvanced MaterialsDec 23, 2022BRONZE OA

Recent Advances in the Use of Covalent Organic Frameworks as Heterogenous Photocatalysts in Organic Synthesis

ALAlberto López‐Magano SDSaba Daliran ARAli Reza Oveisi RMRubén Mas‐Ballesté ADAmarajothi Dhakshinamoorthy

Universidad Autónoma de Madrid · Zabol University · +6 more institutions

PubMed

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Abstract

Organic photochemistry is intensely developed in the 1980s, in which the nature of excited electronic states and the energy and electron transfer processes are thoroughly studied and finally well-understood. This knowledge from molecular organic photochemistry can be transferred to the design of covalent organic frameworks (COFs) as active visible-light photocatalysts. COFs constitute a new class of crystalline porous materials with substantial application potentials. Featured with outstanding structural tunability, large porosity, high surface area, excellent stability, and unique photoelectronic properties, COFs are studied as potential candidates in various research areas (e.g., photocatalysis). This review…

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Topics

Keywords

Photocatalysis
Materials science
Covalent bond
Nanotechnology
Porosity
Covalent organic framework
Crystallinity
Catalysis

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