reviewACS Central ScienceDec 16, 2022DIAMOND OA

Multifunctional Porous Hydrogen-Bonded Organic Frameworks: Current Status and Future Perspectives

ZLZu‐Jin LinSAShaheer A. R. MahammedTLTian‐Fu LiuRCRong Cao

Chinese Academy of Sciences · Fujian Institute of Research on the Structure of Matter · +2 more institutions

PubMed
Indexed incrossrefdoajpubmed

Abstract

Hydrogen-bonded organic frameworks (HOFs), self-assembled from organic or metalated organic building blocks (also termed as tectons) by hydrogen bonding, π-π stacking, and other intermolecular interactions, have become an emerging class of multifunctional porous materials. So far, a library of HOFs with high porosity has been synthesized based on versatile tectons and supramolecular synthons. Benefiting from the flexibility and reversibility of H-bonds, HOFs feature high structural flexibility, mild synthetic reaction, excellent solution processability, facile healing, easy regeneration, and good recyclability. However, the flexible and reversible nature of H-bonds makes most HOFs suffer from poor structural…

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283
total citations
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19.44
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100%
References
165
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Authors

4

Topics & keywords

Topics
Keywords
  • Materials science
  • Nanotechnology
  • Stacking
  • Supramolecular chemistry
  • Flexibility (engineering)
  • Hydrogen bond
  • Metal-organic framework
  • Molecule
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