articleAdvanced MaterialsJan 4, 2023Closed access

Pd–PdO Nanodomains on Amorphous Ru Metallene Oxide for High‐Performance Multifunctional Electrocatalysis

Nanyang Technological University · Université Bourgogne Franche-Comté · +5 more institutions

PubMed
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Abstract

Abstract Developing highly efficient multifunctional electrocatalysts is crucial for future sustainable energy pursuits, but remains a great challenge. Herein, a facile synthetic strategy is used to confine atomically thin Pd–PdO nanodomains to amorphous Ru metallene oxide (RuO 2 ). The as‐synthesized electrocatalyst (Pd 2 RuOx‐0.5 h) exhibits excellent catalytic activity toward the pH‐universal hydrogen evolution reaction (η 10 = 14 mV in 1 m KOH, η 10 = 12 mV in 0.5 m H 2 SO 4 , and η 10 = 22 mV in 1 m PBS), alkaline oxygen evolution reaction (η 10 = 225 mV), and overall water splitting ( E 10 = 1.49 V) with high mass activity and operational stability. Further reduction endows the material (Pd 2 RuOx‐2 h)…

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