articleJournal of the American Chemical SocietyJan 4, 2023Closed access

Hydrogen Bonding Regulated Flexibility and Disorder in Hydrazone-Linked Covalent Organic Frameworks

University of Science and Technology of China · Collaborative Innovation Center of Chemistry for Energy Materials

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Abstract

Covalent organic framework (COF) chemistry is experiencing unprecedented development in recent decades. The current studies on COF chemistry are mainly focused on the discovery of novel covalent linkages, new topological structures, synthetic methodologies, and potential applications. However, despite the fact that noncovalent interactions are ubiquitous in COF chemistry, relatively little attention has been given to the role of noncovalent bonds on COF structures and their properties. In this work, a series of hydrazone-linked COFs involving noncovalent hydrogen bonds have been constructed, where the hydrogen-bonding interaction plays critical roles in the COF crystallinity and structures. The regulation of…

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