articleAdvanced MaterialsJan 7, 2023Closed access

Arming Ru with Oxygen‐Vacancy‐Enriched RuO 2 Sub‐Nanometer Skin Activates Superior Bifunctionality for pH‐Universal Overall Water Splitting

University of Science and Technology of China · Hefei National Center for Physical Sciences at Nanoscale · +1 more institution

PubMed
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Abstract

Abstract Water electrolysis has been expected to assimilate the renewable yet intermediate energy‐derived electricity for green H 2 production. However, current benchmark anodic catalysts of Ir/Ru‐based compounds suffer severely from poor dissolution resistance. Herein, an effective modification strategy is proposed by arming a sub‐nanometer RuO 2 skin with abundant oxygen vacancies to the interconnected Ru clusters/carbon hybrid microsheet (denoted as Ru@V‐RuO 2 /C HMS), which can not only inherit the high hydrogen evolution reaction (HER) activity of the Ru, but more importantly, activate the superior activity toward the oxygen evolution reaction (OER) in both acid and alkaline conditions. Outstandingly, it…

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