Sub-nm RuO x Clusters on Pd Metallene for Synergistically Enhanced Nitrate Electroreduction to Ammonia

The electrochemical nitrate reduction to ammonia reaction (NO3RR) has emerged as an appealing route for achieving both wastewater treatment and ammonia production. Herein, sub-nm RuOx clusters anchored on a Pd metallene (RuOx/Pd) are reported as a highly effective NO3RR catalyst, delivering a maximum NH3-Faradaic efficiency of 98.6% with a corresponding NH3 yield rate of 23.5 mg h–1 cm–2 and partial a current density of 296.3 mA cm–2 at −0.5 V vs RHE. Operando spectroscopic characterizations combined with theoretical computations unveil the synergy of RuOx and Pd to enhance the NO3RR energetics through a mechanism of hydrogen spillover and hydrogen-bond interactions. In detail, RuOx activates NO3– to form…

• NN
  National Natural Science Foundation of China

  Award: 52161025