Construction of Covalent Organic Frameworks via Multicomponent Reactions

Multicomponent reactions (MCRs) combine at least three reactants to afford the desired product in a highly atom-economic way and are therefore viewed as efficient one-pot combinatorial synthesis tools allowing one to significantly boost molecular complexity and diversity. Nowadays, MCRs are no longer confined to organic synthesis and have found applications in materials chemistry. In particular, MCRs can be used to prepare covalent organic frameworks (COFs), which are crystalline porous materials assembled from organic monomers and exhibit a broad range of properties and applications. This synthetic approach retains the advantages of small-molecule MCRs, not only strengthening the skeletal robustness of COFs,…

• NN
  National Natural Science Foundation of China

  Award: 21971153
• NS
  Natural Science Foundation of Shandong Province

  Award: ZR2020ZD32
• TS
  Taishan Scholar Foundation of Shandong Province