Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis

Because sunlight is the most abundant energy source on earth, it has huge potential for practical applications ranging from sustainable energy supply to light driven chemistry. From a chemical perspective, excited states generated by light make thermodynamically uphill reactions possible, which forms the basis for energy storage into fuels. In addition, with light, open-shell species can be generated which open up new reaction pathways in organic synthesis. Crucial are photosensitizers, which absorb light and transfer energy to substrates by various mechanisms, processes that highly depend on the distance between the molecules involved. Supramolecular coordination cages are well studied and synthetically…

• NO
  Nederlandse Organisatie voor Wetenschappelijk Onderzoek
• MV
  Ministerie van Economische Zaken en Klimaat