articleAdvanced MaterialsJan 30, 2023BRONZE OA

Enhancing Photon Utilization Efficiency for High‐Performance Organic Photovoltaic Cells via Regulating Phase‐Transition Kinetics

Chinese Academy of Sciences · Beijing National Laboratory for Molecular Sciences · +5 more institutions

PubMed
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Abstract

Efficient photon utilization is key to achieving high-performance organic photovoltaic (OPV) cells. In this study, a multiscale fibril network morphology in a PBQx-TCl:PBDB-TF:eC9-2Cl-based system is constructed by regulating donor and acceptor phase-transition kinetics. The distinctive phase-transition process and crystal size are systematically investigated. PBQx-TCl and eC9-2Cl form fibril structures with diameters of ≈25 nm in ternary films. Additionally, fine fibrils assembled by PBDB-TF are uniformly distributed over the fibril networks of PBQx-TCl and eC9-2Cl. The ideal multiscale fibril network morphology enables the ternary system to achieve superior charge transfer and transport processes compared to…

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