articleCoordination Chemistry ReviewsFeb 13, 2023HYBRID OA

Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance

University of Vienna

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Abstract

As the structure and properties of anisotropic metal–organic frameworks (MOFs) vary with certain directions in space, controlling the orientation of these MOFs allows full advantage to be taken of their anisotropic properties. Not surprisingly, the preparation of oriented anisotropic MOFs, has drawn great attention in the past decade. In this review, we systematically summarized the strategies utilized for the preparation and growth of oriented MOFs, highlighting the possibilities of each synthetic approach as well as the challenges they have to overcome. Herein, we have also explored the orientation of MOF-on-MOF hybrids. Finally, we have presented the advantages of oriented MOF crystals over their randomly…

Citation impact

368
total citations
FWCI
35.00
Percentile
100%
References
254
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Authors

5

Topics & keywords

Keywords
  • Metal-organic framework
  • Nanotechnology
  • Chemistry
  • Orientation (vector space)
  • Anisotropy
  • Materials science
  • Organic chemistry
  • Physics
UN Sustainable Development Goals
  • Affordable and clean energy
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