articleACS Energy LettersFeb 17, 2023Closed access

Weak Solvent–Solvent Interaction Enables High Stability of Battery Electrolyte

University of Science and Technology of China · Chinese Academy of Sciences · +2 more institutions

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Abstract

Electrolytes play an important role in transporting metal ions (e.g., Li+) in metal ion batteries, while understanding the relationship between the electrolyte properties and behaviors is still challenging. Herein, we detect the existence of weak solvent–solvent interactions in electrolytes by nuclear magnetic resonance (NMR), particularly discovering that such interactions have a significant function of stabilizing the electrolytes, which has never been reported before. As a paradigm, we renovated the understanding of the role of ethylene carbonate (EC) solvent in the lithium-ion battery electrolyte. We find that the EC solvent can stabilize the linear carbonate solvent electrolyte, particularly the diethyl…

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