Zn-Ion Transporting, In Situ Formed Robust Solid Electrolyte Interphase for Stable Zinc Metal Anodes over a Wide Temperature Range

Hydrogen evolution, corrosion, and dendrite formation in the Zn anodes limit their practical applications in aqueous Zn metal batteries. Herein, we propose an interfacial chemistry regulation strategy that uses hybrid electrolytes of water and a polar aprotic N,N-dimethylformamide to modify the Zn2+-solvation structure and in situ form a robust and Zn2+-conducting Zn5(CO3)2(OH)6 solid electrolyte interphase (SEI) on the Zn surface to achieve stable and dendrite-free Zn plating/stripping over a wide temperature range. As confirmed by 67Zn nuclear magnetic resonance relaxometry, electrochemical characterizations, and molecular dynamics simulation, the electrochemically and thermally stable…

• SU
  Sungkyunkwan University
• NR
  National Research Foundation of Korea

  Award: NRF-2020R1A3B2079803
• S
  Samsung