articleAdvanced MaterialsMar 3, 2023BRONZE OA

Achieving High Quantum Efficiency Broadband NIR Mg 4 Ta 2 O 9 :Cr 3+ Phosphor Through Lithium‐Ion Compensation

Nanchang University · Chinese Academy of Sciences · +3 more institutions

PubMed
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Abstract

Abstract Ultra‐efficient broadband near‐infrared (NIR) phosphor‐converted light‐emitting diodes (pc‐LEDs) are urgently needed to improve the detection sensitivity and spatial resolution of current smart NIR spectroscopy‐based techniques. Nonetheless, the performance of NIR pc‐LED has severely limited owing to the external quantum efficiency (EQE) bottleneck of NIR light‐emitting materials. Herein, a blue LED excitable Cr 3+ ‐doped tetramagnesium ditantalate (Mg 4 Ta 2 O 9 , MT) phosphor is advantageously modified through lithium ion as a key efficient broadband NIR emitter to achieve high optical output power of the NIR light source. The emission spectrum encompasses the 700–1300 nm electromagnetic spectrum of…

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