reviewChemical ReviewsMar 10, 2023GREEN OA

Fluids and Electrolytes under Confinement in Single-Digit Nanopores

Walker (United States) · The University of Texas at Austin · +7 more institutions

PubMed
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Abstract

Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics and chemistry that impact the mass transport and energy efficiency in many important natural systems and industrial applications. Existing theories often fail to predict the exotic effects observed in the narrowest of such pores, called single-digit nanopores (SDNs), which have diameters or conduit widths of less than 10 nm, and have only recently become accessible for experimental measurements. What SDNs reveal has been surprising, including a rapidly increasing number of examples such as extraordinarily fast water transport, distorted fluid-phase boundaries, strong ion-correlation and quantum effects, and dielectric…

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