reviewChemical ReviewsApr 6, 2023HYBRID OA

Porous Organic Cages

Chinese Academy of Sciences · Shenzhen Institutes of Advanced Technology · +6 more institutions

PubMed
Indexed incrossrefpubmed

Abstract

Porous organic cages (POCs) are a relatively new class of low-density crystalline materials that have emerged as a versatile platform for investigating molecular recognition, gas storage and separation, and proton conduction, with potential applications in the fields of porous liquids, highly permeable membranes, heterogeneous catalysis, and microreactors. In common with highly extended porous structures, such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and porous organic polymers (POPs), POCs possess all of the advantages of highly specific surface areas, porosities, open pore channels, and tunable structures. In addition, they have discrete molecular structures and exhibit good to…

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