reviewAdvanced MaterialsApr 24, 2023BRONZE OA

Research Progress in Donor−Acceptor Type Covalent Organic Frameworks

University of Science and Technology Beijing · Chinese Academy of Sciences · +2 more institutions

PubMed
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Abstract

Covalent organic frameworks (COFs) are new organic porous materials constructed by covalent bonds, with the advantages of pre-designable topology, adjustable pore size, and abundant active sites. Many research studies have shown that COFs exhibit great potential in gas adsorption, molecular separation, catalysis, drug delivery, energy storage, etc. However, the electrons and holes of intrinsic COF are prone to compounding in transport, and the carrier lifetime is short. The donor-acceptor (D-A) type COFs, which are synthesized by introducing D and A units into the COFs backbone, combine separated electron and hole migration pathway, tunable band gap and optoelectronic properties of D-A type polymers with the…

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