Potential-dependent transition of reaction mechanisms for oxygen evolution on layered double hydroxides

Oxygen evolution reaction (OER) is of crucial importance to sustainable energy and environmental engineering, and layered double hydroxides (LDHs) are among the most active catalysts for OER in alkaline conditions, but the reaction mechanism for OER on LDHs remains controversial. Distinctive types of reaction mechanisms have been proposed for the O-O coupling in OER, yet they compose a coupled reaction network with competing kinetics dependent on applied potentials. Herein, we combine grand-canonical methods and micro-kinetic modeling to unravel that the nature of dominant mechanism for OER on LDHs transitions among distinctive types as a function of applied potential, and this arises from the interplay among…

• NN
  National Natural Science Foundation of China

  Awards: 22122304, 92261111, 2022YFA1503000
• TU
  Tsinghua University

  Award: 20221080065