Coupled Surface-Confinement Effect and Pore Engineering in a Single-Fe-Atom Catalyst for Ultrafast Fenton-like Reaction with High-Valent Iron-Oxo Complex Oxidation
Sichuan University · State Key Laboratory of Hydraulics and Mountain River Engineering · +1 more institution
Abstract
The nanoconfinement effect in Fenton-like reactions shows great potential in environmental remediation, but the construction of confinement structure and the corresponding mechanism are rarely elucidated systematically. Herein, we proposed a novel peroxymonosulfate (PMS) activation system employing the single Fe atom supported on mesoporous N-doped carbon (FeSA-MNC, specific surface area = 1520.9 m2/g), which could accelerate the catalytic oxidation process via the surface-confinement effect. The degradation activity of the confined system was remarkably increased by 34.6 times compared to its analogue unconfined system. The generation of almost 100% high-valent iron-oxo species was identified via 18O…
Citation impact
- FWCI
- 25.29
- Percentile
- 100%
- References
- 66
Authors
10- BHBingkun Huang
Sichuan University, State Key Laboratory of Hydraulics and Mountain River Engineering
- ZWZelin Wu
Sichuan University, State Key Laboratory of Hydraulics and Mountain River Engineering
- XWXinhao Wang
Sichuan University, State Key Laboratory of Hydraulics and Mountain River Engineering
- XSXinyu Song
Sichuan University, State Key Laboratory of Hydraulics and Mountain River Engineering
- HZHongyu Zhou
Sichuan University, State Key Laboratory of Hydraulics and Mountain River Engineering
Topics & keywords
- Catalysis
- Chemistry
- Environmental remediation
- Mesoporous material
- Chemical engineering
- Degradation (telecommunications)
- Adsorption
- Nanotechnology