articleNature CommunicationsOct 9, 2023GOLD OA

Phase regulation enabling dense polymer-based composite electrolytes for solid-state lithium metal batteries

Zhejiang University of Science and Technology · State Key Laboratory of Chemical Engineering · +4 more institutions

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Abstract

Abstract Solid polymer electrolytes with large-scale processability and interfacial compatibility are promising candidates for solid-state lithium metal batteries. Among various systems, poly(vinylidene fluoride)-based polymer electrolytes with residual solvent are appealing for room-temperature battery operations. However, their porous structure and limited ionic conductivity hinder practical application. Herein, we propose a phase regulation strategy to disrupt the symmetry of poly(vinylidene fluoride) chains and obtain the dense composite electrolyte through the incorporation of MoSe 2 sheets. The electrolyte with high dielectric constant can optimize the solvation structures to achieve high ionic…

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