articleAdvanced Energy MaterialsNov 2, 2023Closed access

SnSe 2 /NiSe 2 @N‐Doped Carbon Yolk‐Shell Heterostructure Construction and Selenium Vacancies Engineering for Ultrastable Sodium‐Ion Storage

Qilu University of Technology · Shandong Academy of Sciences · +3 more institutions

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Abstract

Abstract Tin diselenide, a promising anode material for sodium ion batteries (SIBs), still faces sluggish Na + diffusion kinetics and severe volume change, resulting in undesirable cycling stability and rate capability. Heterostructure construction is an effective strategy for boosting Na + storage of SnSe 2 . Herein, an appealing yolk‐shell nanostructure of SnSe 2 /NiSe 2 heterointerface with rich Se vacancies embedded into N‐doped carbon (SnSe 2 /NiSe 2 @NC) is precisely designed through a facile hydrothermal process followed by a selenization strategy. The experimental studies coupled with theoretical calculations results verify that the heterostructure interfaces and Se vacancies accelerate the charge and…

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