Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells

Compared with the n-i-p structure, inverted (p-i-n) perovskite solar cells (PSCs) promise increased operating stability, but these photovoltaic cells often exhibit lower power conversion efficiencies (PCEs) because of nonradiative recombination losses, particularly at the perovskite/C 60 interface. We passivated surface defects and enabled reflection of minority carriers from the interface into the bulk using two types of functional molecules. We used sulfur-modified methylthio molecules to passivate surface defects and suppress recombination through strong coordination and hydrogen bonding, along with diammonium molecules to repel minority carriers and reduce contact-induced interface recombination achieved…

• NS
  National Science Foundation
• NU
  Northwestern University
• SF
  Sherman Fairchild Foundation
• MR
  Materials Research Science and Engineering Center, Harvard University
• OO
  Office of Naval Research
• DO
  Division of Materials Research
• AR
  Army Research Office