Universal F4‐Modified Strategy on Metal–Organic Framework to Chemical Stabilize PVDF‐HFP as Quasi‐Solid‐State Electrolyte
Shaanxi University of Science and Technology · King Abdullah University of Science and Technology · +2 more institutions
Abstract
Abstract Solid‐state electrolytes (SSEs) based on metal organic framework (MOF) and polymer mixed matrix membranes (MMMs) have shown great promotions in both lithium‐ion conduction and interfacial resistance in lithium metal batteries (LMBs). However, the unwanted structural evolution and the and the obscure electrochemical reaction mechanism among two phases limit their further optimization and commercial application. Herein, fluorine‐modified zirconium MOF with diverse F‐quantities is synthesized, denoted as Zr‐BDC‐Fx (x = 0, 2, 4), to assemble high performance quais‐solid‐state electrolytes (QSSEs) with PVDF‐HFP. The chemical complexation of F‐sites in Zr‐BDC‐F 4 stabilized PVDF‐HFP chains in β‐phase and…
Citation impact
- FWCI
- 22.43
- Percentile
- 100%
- References
- 52
Authors
8- WHWenhuan HuangCorresponding
Shaanxi University of Science and Technology
- SWShun Wang
Shaanxi University of Science and Technology
- XZXingxing Zhang
Shaanxi University of Science and Technology
- YKYifan Kang
Shaanxi University of Science and Technology
- HZHuabin Zhang
King Abdullah University of Science and Technology
Topics & keywords
- Materials science
- Electrolyte
- Zirconium
- Electrochemistry
- Chemical engineering
- Lithium (medication)
- Membrane
- Fast ion conductor