articleApplied Catalysis B: EnvironmentalJan 4, 2024HYBRID OA

S-vacancy-rich NiFe-S nanosheets based on a fully electrochemical strategy for large-scale and quasi-industrial OER catalysts

University of Electronic Science and Technology of China · Pennsylvania State University

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Abstract

The oxygen evolution reaction (OER) is regarded as a critical component in the water splitting system. Creating vacancies, increasing active surface area , and optimizing electronic structure would improve electrocatalytic performance. Herein, a facile electrochemical reduction method is used to generate sulfur vacancies in nickel iron sulfide (NiFe-S) with a large geometry area of 15 × 16 cm 2 , which is synthesized using an electrodeposition process assisted with the ion exchange (IOE) method. The X-ray absorption spectroscopies (XAS) are applied for atomic-level structural analysis, verifying that electrochemical desulfurization generates abundant S vacancies . The NiFe-S with abundant sulfur vacancies…

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