articleAngewandte Chemie International EditionJan 17, 2024Closed access

Microwave‐Assisted Rapid Synthesis of MOF‐Based Single‐Atom Ni Catalyst for CO 2 Electroreduction at Ampere‐Level Current

University of Science and Technology of China · Zhengzhou University · +1 more institution

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Abstract

Abstract Carbon‐based single‐atom catalysts (SACs) have attracted tremendous interest in heterogeneous catalysis. However, the common electric heating techniques to produce carbon‐based SACs usually suffer from prolonged heating time and tedious operations. Herein, a general and facile microwave‐assisted rapid pyrolysis method is developed to afford carbon‐based SACs within 3 min without inert gas protection. The obtained carbon‐based SACs present high porosity and comparable carbonization degree to those obtained by electric heating techniques. Specifically, the single‐atom Ni implanted N‐doped carbon (Ni 1 −N−C) derived from a Ni‐doped metal–organic framework (Ni‐ZIF‐8) exhibits remarkable CO Faradaic…

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