articleNature CommunicationsJan 26, 2024GOLD OA

A contact-electro-catalysis process for producing reactive oxygen species by ball milling of triboelectric materials

Georgia Institute of Technology · Chinese Academy of Sciences · +5 more institutions

PubMed
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Abstract

Ball milling is a representative mechanochemical strategy that uses the mechanical agitation-induced effects, defects, or extreme conditions to activate substrates. Here, we demonstrate that ball grinding could bring about contact-electro-catalysis (CEC) by using inert and conventional triboelectric materials. Exemplified by a liquid-assisted-grinding setup involving polytetrafluoroethylene (PTFE), reactive oxygen species (ROS) are produced, despite PTFE being generally considered as catalytically inert. The formation of ROS occurs with various polymers, such as polydimethylsiloxane (PDMS) and polypropylene (PP), and the amount of generated ROS aligns well with the polymers' contact-electrification abilities.…

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