Nanoconfinement-triggered oligomerization pathway for efficient removal of phenolic pollutants via a Fenton-like reaction
Nanjing University of Science and Technology · State Key Laboratory of Pollution Control and Resource Reuse · +4 more institutions
Abstract
Abstract Heterogeneous Fenton reaction represents one of the most reliable technologies to ensure water safety, but is currently challenged by the sluggish Fe(III) reduction, excessive input of chemicals for organic mineralization, and undesirable carbon emission. Current endeavors to improve the catalytic performance of Fenton reaction are mostly focused on how to accelerate Fe(III) reduction, while the pollutant degradation step is habitually overlooked. Here, we report a nanoconfinement strategy by using graphene aerogel (GA) to support UiO-66-NH 2 -(Zr) binding atomic Fe(III), which alters the carbon transfer route during phenol removal from kinetically favored ring-opening route to thermodynamically…
Citation impact
- FWCI
- 17.66
- Percentile
- 100%
- References
- 60
Authors
8- XZXiang ZhangCorresponding
Nanjing University of Science and Technology, State Key Laboratory of Pollution Control and Resource Reuse
- JTJingjing Tang
Nanjing University of Science and Technology, State Key Laboratory of Pollution Control and Resource Reuse
- LWLingling Wang
Nanjing University of Science and Technology, State Key Laboratory of Pollution Control and Resource Reuse
- CWChuan Wang
Nanjing University of Science and Technology, State Key Laboratory of Pollution Control and Resource Reuse
- LCLei Chen
State Key Laboratory of Pollution Control and Resource Reuse, Nanjing University
Topics & keywords
- Phenol
- Catalysis
- Mineralization (soil science)
- Chemistry
- Pollutant
- Aqueous solution
- Aerogel
- Carbon fibers
- Clean water and sanitation