Hierarchical Li electrochemistry using alloy-type anode for high-energy-density Li metal batteries

Exploiting thin Li metal anode is essential for high-energy-density battery, but is severely plagued by the poor processability of Li, as well as the uncontrollable Li plating/stripping behaviors and Li/electrolyte interface. Herein, a thickness/capacity-adjustable thin alloy-type Li/LiZn@Cu anode is fabricated for high-energy-density Li metal batteries. The as-formed lithophilic LiZn alloy in Li/LiZn@Cu anode can effectively regulate Li plating/stripping and stabilize the Li/electrolyte interface to deliver the hierarchical Li electrochemistry. Upon charging, the Li/LiZn@Cu anode firstly acts as Li source for homogeneous Li extraction. At the end of charging, the de-alloy of LiZn nanostructures further…

• NS
  National Supercomputer Centre in Guangzhou
• NS
  Natural Science Foundation of Guangdong Province

  Awards: 2021B1515120002, 2022A1515010405
• NN
  National Natural Science Foundation of China-Yunnan Joint Fund

  Award: 22075328，22379168