articleAdvanced Energy MaterialsFeb 25, 2024Closed access

High Voltage Electrolyte Design Mediated by Advanced Solvation Chemistry Toward High Energy Density and Fast Charging Lithium‐Ion Batteries

University of Science and Technology of China · Chinese Academy of Sciences · +4 more institutions

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Abstract

Abstract Electrolyte is critical for transporting lithium‐ion (Li + ) in lithium‐ion batteries (LIBs). However, there is no universally applicable principle for designing an optimal electrolyte. In most cases, the design process relies on empirical experiences and is often treated as highly confidential proprietary information. Herein, a solvation structure‐related model for the quantitative design of electrolytes is introduced, focusing on the principles of coordination chemistry. As a paradigmatic example, a high‐voltage electrolyte (i.e., 4.5 V vs anode) aimed at achieving a high energy density and fast charging LIB, which is specifically composed of an emerging, well‐constructed hybrid hard…

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