articleAdvanced ScienceFeb 28, 2024GOLD OA

Metal Sulfide S‐Scheme Homojunction for Photocatalytic Selective Phenylcarbinol Oxidation

Huaibei Normal University · KU Leuven · +7 more institutions

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Abstract

Abstract Metal sulfide‐based homojunction photocatalysts are extensively explored with improved photocatalytic performance. However, the construction of metal sulfide‐based S‐scheme homojunction remains a challenge. Herein, the fabrication of 2D CdIn 2 S 4 nanosheets coated 3D CdIn 2 S 4 octahedra (referred to as 2D/3D n‐CIS/o‐CIS) S‐scheme homojunction photocatalyst is reported by simply adjustment of polyvinyl pyrrolidone amount during the solvothermal synthesis. The formation of S‐scheme homojunction within n‐CIS/o‐CIS is systematically investigated via a series of characterizations, which can generate an internal electric field to facilitate the separation and migration of photogenerated electron‐hole…

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